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Chlorine : Aqueous Hydrochloric Acid



Hydrogen chloride is very soluble in water. When 1 kgm. of water is saturated with the gas at 15° it increases in weight to 1.75 kgm., and the density is 1.231. It contains about 43 per cent, of HCl; the commercial acid contains about 39 per cent., its density being 1.20.

Densities of aqueous solutions of hydrochloric acid at 15°.

DensityPer cent. HCl
1.049110
1.078415.84
1.101420.29
1.127125.18
1.149029.35
1.169633.39
1.190137.23
1.200239.15


Expt. 17. - The great solubility of hydrochloric acid gas in water may be demonstrated by the fountain experiment. A large round-bottomed flask is filled with the gas by displacement (this takes some time) and fitted with a rubber stopper carrying a tube drawn out inside the flask into a jet. The flask is inverted with the tube dipping into water coloured with blue litmus contained in a second large flask, as shown in.
Demonstration of the solubility of hydrogen chloride

Fig: Demonstration of the solubility of hydrogen chloride


By blowing into the short tube on the second flask a drop of water is forced into the upper flask. The gas is instantly dissolved, the atmospheric pressure forces the water in the lower flask in the form of a fountain into the upper flask, and the litmus is turned red by the acid solution formed.



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